P223 · Precautionary statementDo not allow contact with water.

Precautionary · PreventionPhysical

P223 is the GHS precautionary statement “Do not allow contact with water”. UN GHS Annex 3 assigns it to Substances and mixtures which, in contact with water, emit flammable gases (chapter 2.12), Category 1, 2. The English wording is the same as UN GHS Rev.11 in US OSHA, EU CLP and Canada. Canada’s official French text is “Éviter tout contact avec l'eau” and Mexico’s Spanish text is “Evitar el contacto con el agua”. In the UN GHS Rev.11 label matrix it is used with 2 hazard statements (UN only).

Heading text: UN GHS Rev.11 Annex 3. Wording can differ by jurisdiction; see the table below.

Wording by jurisdiction

UN GHS Rev.11

Same as UN
GHS Rev.11 (2025), Annex 3

Do not allow contact with water.

UN GHS Rev.11, Annex 3, Table A3.2.2, PDF p. 315

US OSHA HCS

Same as UN
HCS 2024 · primarily GHS Rev.7, some Rev.8

Do not allow contact with water.

29 CFR 1910.1200 App. C, matched by wording

EU CLP

Same as UN
EU_CLP_2025 · consolidated 1 Jul 2026

Do not allow contact with water.

EU CLP, Annex IV, Part 2

Canada (EN)

Same as UN
WHMIS_2022 · GHS Rev.7 (Rev.8 for chemicals under pressure)

Do not allow contact with water.

GHS Rev.7 Annex 3 Table A3.2

Canada (FR)

Adopted
WHMIS_2022 · SGH Rév.7, texte officiel

Éviter tout contact avec l'eau.

GHS Rev.7 Annex 3 Table A3.2

Mexico (ES)

Adopted
NOM-018-STPS-2015 · GHS 5th revised edition

Evitar el contacto con el agua

NOM-018-STPS-2015, DOF 9 October 2015, Apéndice D, Tabla D.1, PDF p. 35

Hazard classes and categories

  • Substances and mixtures which, in contact with water, emit flammable gases (chapter 2.12) · Category 1, 2

UN GHS Rev.11 Annex 3, sections 1 and 2

UN GHS Rev.11 only. EU CLP, US OSHA, Canada (GHS Rev.7) and Mexico assign their own P statements; check the regulation for your market.

UN GHS Rev.11 Annex 3, section 3. Listed for at least one category that uses each H statement.

Conditions for use

  • if emphasis of the hazard statement is deemed necessary.

Quoted as published in UN GHS Rev.11 Annex 3, section 2. List markers are shown as bullets.

Change in UN GHS Rev.11

No change to the wording or the hazard classes in Annex 3 compared with Rev.10.

Sources

Each cell in the table names the official table and page for P223. Full citations, links and revision notes for UN GHS Rev.11, US OSHA, EU CLP, Canada and Mexico: Sources and revision notes.

These are regulatory phrases for labels and safety data sheets. Check them against the official source for your jurisdiction before use.

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